Sprinkle chicken with 1/4 teaspoon salt and pepper.
Heat a large nonstick skillet over medium-high heat.
Add oil to pan; swirl to coat.
Add half of chicken to pan; cook 5 minutes on each side or until lightly browned.
Place chicken in a 5-quart electric slow cooker coated with cooking spray. Repeat procedure with remaining chicken.
Place mushrooms on top of chicken.
Add garlic, onion, and bell peppers to pan; sprinkle vegetables with remaining 1/4 teaspoon salt. Reduce heat to medium, and cook 5 minutes or until vegetables are crisp-tender, stirring often.
Add wine, scraping pan to loosen brown bits. Cook 1 minute. Stir in flour. Stir in oregano, thyme, and tomatoes.
Pour tomato mixture over mushrooms in slow cooker. Cover and cook on LOW for 3 hours or until chicken is very tender.