Line baking sheet with parchment paper; coat parchment paper with cooking spray.
Preheat oven to 35
Stir together nectarines, peaches, and next 4 ingredients in a large bowl.
Let stand 30 minutes, stirring occasionally.
Unroll piecrust on prepared baking sheet.
Roll into a 12-inch circle.
Drain fruit mixture, reserving liquid. Toss nectarines and peaches in flour.
Mound nectarines and peaches in center of piecrust, leaving a 3-inch border. Fold piecrust border up and over fruit, pleating as you go, leaving an opening about 5 inches wide in center.
Stir together egg and 1 Tbsp. water.
Brush piecrust with egg mixture, and sprinkle with 1 Tbsp. sugar.
Bake at 350 for 45 minutes or until filling is bubbly and crust is golden. Carefully transfer tart on parchment paper to a wire rack; cool 20 minutes.
Meanwhile, bring reserved nectarine-peach liquid to a boil in a small saucepan over medium heat. Boil 1 to 2 minutes or until slightly thickened.
Let cool slightly.
Brush or drizzle 1 to 2 Tbsp. hot nectarine-peach liquid over exposed fruit in center of tart.
Serve immediately with remaining nectarine-peach syrup, and, if desired, Sweet Cream Topping.