To prepare guacamole, wrap garlic cloves in foil; bake at 450 for 15 minutes or until soft.
Let cool slightly; remove skins.
Place garlic in a medium bowl; mash with a fork.
Preheat broiler.
Cut peppers in half lengthwise; discard seeds and membranes.
Place pepper halves, skin sides up, on a foil-lined baking sheet; flatten with hand. Broil 15 minutes or until blackened, turning frequently.
Place in a zip-top plastic bag; seal.
Let stand 10 minutes. Peel and finely chop.
Add peppers, onions, and next 4 ingredients (through avocado) to mashed garlic; stir well.
Reduce heat to 42
To prepare chips, combine tortilla wedges, 2 teaspoons juice, and 1/4 teaspoon salt in a large bowl, tossing to coat. Arrange the tortillas in a single layer on a baking sheet coated with cooking spray.
Bake at 425 for 10 minutes or until crisp and lightly browned, turning once. Cool 5 minutes.